| Handheld XRF with Si-PIN detector | Stainless and low-alloy steels, copper and nickel alloys, precious metals | Titanium upwards (Cr, Fe, Ni, Cu, Mo, Au and others); light elements unreliable | No | Sorting clearly different alloys, gold and silver fineness | When alloys differ in heavy elements and volumes are modest |
| Handheld XRF with SDD detector | All metal families, including aluminium, magnesium and titanium alloys | Magnesium upwards; Mg, Al, Si, P and S in air with higher limits | No | Goods-in against EN 10204 certificates, oil & gas (API RP 578), scrap, foundry, gold, ores | As the general-purpose PMI analyzer, with many alloys and short tests |
| Handheld LIBS (argon-purged for carbon) | Carbon and stainless steels, aluminium, light alloys | Light elements too (Li, Be, B, C, Mg, Al, Si) | Yes, on argon-purged models and clean metal | Telling 304/304L and 316/316L apart, carbon in steels to be welded | When the specification hinges on carbon; leaves a micro ablation crater |
| Spark OES (mobile or laboratory), for comparison | Steels, cast irons, aluminium, copper, nickel | All, with C, P, S and B at low concentrations too | Yes, with lower limits than handheld techniques | Melt control in the foundry, chemical certification, referee analysis | When you need certificate-grade data or the sample can go to a lab |